cop98#8_ic#o4.dat
Resolved Specific Ion Data Collections
- Ion
- O4+
- Temperature Range
- 2.154 eV → 431 eV
ADF04
- Filename
- cop98#8_ic#o4.dat
- Full Path
- adf04/adas#8/cop98#8_ic#o4.dat
Download data
- Spontaneous Emission: O+4(i) → O+4(j) + hv
- Electron Impact Excitation: O+4(i) + e → O+4(j) + e
| 1s2 2s2 1S0.0 | 0.0 cm-1 |
| 1s2 2s2p 3P0.0 | 81942.5 cm-1 |
| 1s2 2s2p 3P1.0 | 82078.6 cm-1 |
| 1s2 2s2p 3P2.0 | 82385.3 cm-1 |
| 1s2 2s2p 1P1.0 | 158798.0 cm-1 |
| 1s2 2p2 3P0.0 | 213462.0 cm-1 |
| 1s2 2p2 3P1.0 | 213618.0 cm-1 |
| 1s2 2p2 3P2.0 | 213887.0 cm-1 |
| 1s2 2p2 1D2.0 | 231721.0 cm-1 |
| 1s2 2p2 1S0.0 | 287910.0 cm-1 |
| 1s2 2s1 3s1 3S1.0 | 546973.0 cm-1 |
| 1s2 2s1 3s1 1S0.0 | 561276.0 cm-1 |
| 1s2 2s1 3p1 3P0.0 | 582806.0 cm-1 |
| 1s2 2s1 3p1 3P1.0 | 582843.0 cm-1 |
| 1s2 2s1 3p1 3P2.0 | 582920.0 cm-1 |
| 1s2 2s1 3p1 1P1.0 | 580825.0 cm-1 |
| 1s2 2s1 3d1 3D1.0 | 600749.0 cm-1 |
| 1s2 2s1 3d1 3D2.0 | 600759.0 cm-1 |
| 1s2 2s1 3d1 3D3.0 | 600779.0 cm-1 |
| 1s2 2s1 3d1 1D2.0 | 612616.0 cm-1 |
| 1s2 2p1 3s1 3P0.0 | 652915.0 cm-1 |
| 1s2 2p1 3s1 3P1.0 | 653077.0 cm-1 |
| 1s2 2p1 3s1 3P2.0 | 653420.0 cm-1 |
| 1s2 2p1 3s1 1P1.0 | 664486.0 cm-1 |
| 1s2 2p1 3p1 1P1.0 | 672694.0 cm-1 |
| 1s2 2p1 3p1 3D1.0 | 677147.0 cm-1 |
| 1s2 2p1 3p1 3D2.0 | 677345.0 cm-1 |
| 1s2 2p1 3p1 3D3.0 | 677662.0 cm-1 |
| 1s2 2p1 3p1 3S1.0 | 683940.0 cm-1 |
| 1s2 2p1 3p1 3P0.0 | 689400.0 cm-1 |
| 1s2 2p1 3p1 3P1.0 | 689514.0 cm-1 |
| 1s2 2p1 3p1 3P2.0 | 689705.0 cm-1 |
| 1s2 2p1 3d1 3F2.0 | 692623.0 cm-1 |
| 1s2 2p1 3d1 3F3.0 | 692806.0 cm-1 |
| 1s2 2p1 3d1 3F4.0 | 693042.0 cm-1 |
| 1s2 2p1 3d1 1D2.0 | 694644.0 cm-1 |
| 1s2 2p1 3p1 1D2.0 | 697170.0 cm-1 |
| 1s2 2p1 3d1 3D1.0 | 704179.0 cm-1 |
| 1s2 2p1 3d1 3D2.0 | 704239.0 cm-1 |
| 1s2 2p1 3d1 3D3.0 | 704345.0 cm-1 |
| 1s2 2p1 3d1 3P2.0 | 707978.0 cm-1 |
| 1s2 2p1 3d1 3P1.0 | 708122.0 cm-1 |
| 1s2 2p1 3d1 3P0.0 | 708202.0 cm-1 |
| 1s2 2p1 3p1 1S0.0 | 707636.0 cm-1 |
| 1s2 2p1 3d1 1F3.0 | 712964.0 cm-1 |
| 1s2 2p1 3d1 1P1.0 | 719275.0 cm-1 |
| 1s2 2s1 4s1 3S1.0 | 722477.0 cm-1 |
| 1s2 2s1 4s1 1S0.0 | 731670.0 cm-1 |
| 1s2 2s1 4p1 3P0.0 | 735908.0 cm-1 |
| 1s2 2s1 4p1 3P1.0 | 735919.0 cm-1 |
| 1s2 2s1 4p1 3P2.0 | 735946.0 cm-1 |
| 1s2 2s1 4p1 1P1.0 | 737881.0 cm-1 |
| 1s2 2s1 4d1 3D1.0 | 742236.0 cm-1 |
| 1s2 2s1 4d1 3D2.0 | 742241.0 cm-1 |
| 1s2 2s1 4d1 3D3.0 | 742245.0 cm-1 |
| 1s2 2s1 4d1 1D2.0 | 746275.0 cm-1 |
| 1s2 2s1 4f1 3F2.0 | 747547.0 cm-1 |
| 1s2 2s1 4f1 3F3.0 | 747547.0 cm-1 |
| 1s2 2s1 4f1 3F4.0 | 747547.0 cm-1 |
| 1s2 2s1 4f1 1F3.0 | 749840.0 cm-1 |
| 1s2 2s1 5s1 3S1.0 | 796068.0 cm-1 |
| 1s2 2s1 5s1 1S0.0 | 801078.0 cm-1 |
| 1s2 2s1 5p1 3P0.0 | 802859.0 cm-1 |
| 1s2 2s1 5p1 3P1.0 | 802859.0 cm-1 |
| 1s2 2s1 5p1 3P2.0 | 802875.0 cm-1 |
| 1s2 2s1 5p1 1P1.0 | 802466.0 cm-1 |
| 1s2 2s1 5d1 3D1.0 | 806443.0 cm-1 |
| 1s2 2s1 5d1 3D2.0 | 806445.0 cm-1 |
| 1s2 2s1 5d1 3D3.0 | 806448.0 cm-1 |
| 1s2 2s1 5f1 3F2.0 | 808610.0 cm-1 |
| 1s2 2s1 5f1 3F3.0 | 808611.0 cm-1 |
| 1s2 2s1 5f1 3F4.0 | 808613.0 cm-1 |
| 1s2 2s1 5d1 1D2.0 | 808352.0 cm-1 |
| 1s2 2s1 5f1 1F3.0 | 808917.0 cm-1 |
| 1s2 2s1 5g1 3G3.0 | 808385.0 cm-1 |
| 1s2 2s1 5g1 3G4.0 | 808385.0 cm-1 |
| 1s2 2s1 5g1 3G5.0 | 808389.0 cm-1 |
| 1s2 2s1 5g1 1G4.0 | 808389.0 cm-1 |
Contributors
- Martin O'Mullane
- Hugh Summers
------------------------------------------------------------------------------- Combined two specific ion files Target : /u/hps/adas/adf04/cop98#8/copmm#8_ic#o4.dat Supplementary : /u/hps/adas/adf04/cop98#8/copjl#be_ic#o4.dat Replace SUPPLEMENTARY level into TARGET level 1 1 2 2 3 3 4 4 5 5 6 6 7 7 8 8 9 9 10 10 11 11 12 12 13 16 14 13 15 14 16 15 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 59 59 60 60 61 61 62 62 63 63 64 64 65 65 66 66 67 67 68 68 69 69 70 70 71 71 72 72 73 73 74 74 75 75 76 76 77 77 78 78 Code : /u/hps/merge_adf04/merge_adf04 ------------------------------------------------------------------------------- A value differences were detected for the following transitions Tran. Target Supp 6 1 0.00D+00 1.00D-30 10 1 0.00D+00 1.00D-30 12 1 0.00D+00 1.00D-30 18 1 5.94D+00 1.00D-30 8 6 1.28D-10 9.64D-11 9 6 1.15D-07 1.10D-07 10 6 0.00D+00 1.00D-30 12 6 0.00D+00 1.00D-30 18 6 6.86D+02 1.00D-30 20 6 2.59D+00 1.00D-30 11 7 1.93D-04 1.00D-30 17 7 1.55D+03 1.00D-30 18 7 1.72D+02 1.00D-30 19 7 6.78D+02 1.00D-30 20 7 8.11D-03 1.00D-30 11 8 6.13D-04 1.00D-30 12 8 4.99D+00 1.00D-30 17 8 5.12D+02 1.00D-30 18 8 1.19D+03 1.00D-30 19 8 1.35D+03 1.00D-30 20 8 6.49D-01 1.00D-30 11 9 2.74D-03 1.00D-30 12 9 3.54D+04 1.00D-30 17 9 3.73D-03 1.00D-30 18 9 9.90D-02 1.00D-30 19 9 1.06D-01 1.00D-30 20 9 4.57D+03 1.00D-30 12 10 0.00D+00 1.00D-30 18 10 8.55D-03 1.00D-30 20 10 2.32D+04 1.00D-30 17 11 2.32D+02 1.00D-30 18 11 2.32D+02 1.00D-30 19 11 2.33D+02 1.00D-30 20 11 7.22D-04 1.00D-30 18 12 7.05D-05 1.00D-30 20 12 2.00D+02 1.00D-30 20 17 3.70D-05 1.00D-30 20 18 6.85D-06 1.00D-30 20 19 3.80D-05 1.00D-30 4 2 4.42D-05 1.28D-10 13 2 0.00D+00 1.00D-30 16 3 5.03D+02 1.00D-30 16 4 1.17D+03 1.00D-30 14 5 7.09D+02 1.00D-30 15 5 1.59D+00 1.00D-30 15 13 1.97D+03 1.00D-30 15 14 6.70D-06 1.00D-30 16 14 4.66D-05 1.00D-30 16 15 6.41D-05 1.00D-30 16 11 2.81D+05 1.00D-30 Choice of A values for the following transitions has been made 6 1, 10 1, 12 1, 18 1, 8 6, 9 6, 10 6, 12 6 18 6, 20 6, 11 7, 17 7, 18 7, 19 7, 20 7, 11 8 12 8, 17 8, 18 8, 19 8, 20 8, 11 9, 12 9, 17 9 18 9, 19 9, 20 9, 12 10, 18 10, 20 10, 17 11, 18 11 19 11, 20 11, 18 12, 20 12, 20 17, 20 18, 20 19, 4 2 13 2, 16 3, 16 4, 14 5, 15 5, 15 13, 15 14, 16 14 16 15, 16 11 ------------------------------------------------------------------------------- For the following transitions target A values have been preferred Tran. Target Supp 18 1 5.94D+00 1.00D-30 18 6 6.86D+02 1.00D-30 20 6 2.59D+00 1.00D-30 11 7 1.93D-04 1.00D-30 17 7 1.55D+03 1.00D-30 18 7 1.72D+02 1.00D-30 19 7 6.78D+02 1.00D-30 20 7 8.11D-03 1.00D-30 11 8 6.13D-04 1.00D-30 12 8 4.99D+00 1.00D-30 17 8 5.12D+02 1.00D-30 18 8 1.19D+03 1.00D-30 19 8 1.35D+03 1.00D-30 20 8 6.49D-01 1.00D-30 11 9 2.74D-03 1.00D-30 12 9 3.54D+04 1.00D-30 17 9 3.73D-03 1.00D-30 18 9 9.90D-02 1.00D-30 19 9 1.06D-01 1.00D-30 20 9 4.57D+03 1.00D-30 18 10 8.55D-03 1.00D-30 20 10 2.32D+04 1.00D-30 17 11 2.32D+02 1.00D-30 18 11 2.32D+02 1.00D-30 19 11 2.33D+02 1.00D-30 20 11 7.22D-04 1.00D-30 18 12 7.05D-05 1.00D-30 20 12 2.00D+02 1.00D-30 20 17 3.70D-05 1.00D-30 20 18 6.85D-06 1.00D-30 20 19 3.80D-05 1.00D-30 4 2 4.42D-05 1.28D-10 15 2 5.09D-04 1.93D+05 16 3 5.03D+02 1.00D-30 16 4 1.17D+03 1.00D-30 14 5 7.09D+02 1.00D-30 15 5 1.59D+00 1.00D-30 15 13 1.97D+03 1.00D-30 15 14 6.70D-06 1.00D-30 16 14 4.66D-05 1.00D-30 16 15 6.41D-05 1.00D-30 16 6 3.86D+04 1.84D+03 16 11 2.81D+05 1.00D-30 12 3 1.05D+05 1.06D+04 ------------------------------------------------------------------------------- Comments from target file --------------------------------------------------------------------------------- Generated from Cowan Atomic Structure Program From IFG file : JETXPQ.IFG#BE.ARCHIVE(O4#A) M O'Mullane 15:33 6/10/1998 SCF method used : HR Scale factors for Slater Parameters : 85 99 75 80 65 Optically allowed transitions : yes Optically forbidden transitions M1 : both Optically forbidden transitions E2 : both Born Collision-Strength - print : 9 - forbidden : 0 -> 2 - allowed : 1 -> 1 - included : 10,all Parity 1 Parity 2 Allowed 492 593 903 initially 492 593 903 reduced --------------------------------------------------------------------------------- Update: 13/11/98 HP Summers Adjusted energy levels from NIST (DAS) data Missing 2s5s (1S) level obtained from qd. --------------------------------------------------------------------------------- Comments from supplementary file ----------------------------------------------------------------------- The effective collision strengths are calculated using the fit parameters of Kato,Lang,& Berrington 1990 (Atomic Data and Nuclear Data Tables 44,133),and the analytical formulae (3 & 4) therein. The data for transition probabilities among the n=2 and n=3 levels should be taken from Hibbert,A 1980 (J.Phys.B 13,1721) but are currently the ones used for the Belike data in JL1990O, location : jetshp.belike.data(jl1990o). D Brooks & J LANG july 1994. *Corrections* The fit parameters for the transition 2s3s(3S1)-2s2p(3P) i.e.11-2,3,4 published in Kato et al.(1990) were incorrect.We altered these in the data set after being sent the correct values by T.Kato. Fit parameters for the fine structure transitions between levels of the term 2p2(3P) i.e.6,7,8 produce gammas which compare well to the ones from belike_jl1990o.dat but the rate coefficients calculated from these gammas (using the formula in Kato et al.) do not match the graphs published in Kato et al. *comment* The new data compare reasonably well with the belike_jl1990o.dat set. The largest discrepancies >50% (where comparison data is available) are; 2p2(3P) - 2s2(1S0) 6,7,8 - 1 +93.4% 2p2(3P2) - 2s2p(3P0) 8 - 2 +61.1% 2p2(1S0) - 2s2p(3P) 10 - 2,3,4 +105.4% 2p2(3P0) - 2s2p(3P2) 6 - 4 +60.6% D.H.Brooks 2.11.94 *Update* A number of further errors and publishing mistakes were found by J.Lang and T.Kato and also myself. Following communications between us, corrections affecting the following transitions were made. 1-11, 5-12, 12-20, 8-16, 17-20, 18-20, 19-20, 6-8, 7-8 In addition, all the effective collision strengths were compared to the original Belfast calculations at 500,000 K and the following transitions were found to be reproduced to worse than 10%. 15-18 to 11.9%, 16-18 to 14.9%, 6-14 to 15.4%, 15-19 to 15.9% 8-14 to 18.9%, 17-18 to 22.7%, 18-19 to 25%, 6-8 to 38%, 7-8 to 52.7% In fact the alterations have accentuated the differences between the 1990 & 1994 data for the 6-8,7-8 transitions. The comments on this comparison (above) are unaffected. D.H.Brooks 16.08.95 Update 25 Sept 98 Energy levels The results from NSRDS NBS3 SECT 4 were used. These were within 2.5 wavenumbers of the results of Edlen (Phys. Scr 32, 86, 1985 and 28, 51, 1983) who only considered n=2 levels. The NSRDS values are also those of Moore and Gallacher "Tables of Spectra of Hydrogen, Carbon, Nitrogen and Oxygen atoms and ions" CRC press 1993. They agree to within 4 wavenumbers with the NIST Standard Ref Database 61, NIST Database for Atomic Spectrocopy Version 1.0. Transition Probabilities The A values have also been updated. Since the file was created, the assessed data from Wiese, Fuhr and Deters 'Atomic Transition Probabilities of Carbon, Nitrogen and Oxygen, A Critical Data Compilation' J Phys Chem Ref Data Mono 7, 1996 have been published. This is used for all A values except as given below. They use unpublished data of Weiss and results from the Opcity Project (for Be sequence Tully, Seaton and Berrington J Phys B 23, 381 1991). The Opacity Project wrok was in LS coupling and they justify spliitng the data by LS rules by comparison with published work. They say that the earlier review by Allard et al (see above) also used Opacity Project data as well as earlier work. The 1996 compilation gives a zero weight to the earlier work while Allard et al gave it a weight of 1 and Opacity results a weight of 5. There is only a slight difference from the 1996 work and Allard et al. Since the critical compilation was done there have been some further results published. Fleming et al (Phys Scr 53,446,1996) published the oscillator strength for the 2s2 1S - 2s2p 1P line obtaining 0.511 and 0.510 cf assessed value of 0.5123. This last value is in agreement with the work of Jonsson, Froese Fischer and Trabert (J Phys B 31, 3497, 1998) in a MCDF calculation while Ynnerman and Froese Fischer (Phys Rev A 51 2020, 1995) give 0.508 from a MCDF calculation. We adopt the compilation value. Fleming et al (MNRAS 279, 1289, 1996) give CIV3 results for the 2s2 1S - 2s 2p 3P1 and 3P2 transitions of 2283 and 2.16 -2 s-1 respectively. For the 1S -3P1 transition this should be compared to the compilation result of 2340 s-1, that of Ralchenko and Vainstein (Phys Rev A 52, 2449, 1995) of 2540 s-1, that of Ynnerman and Froese Fischer of 2210 s-1 and Jonsson, Froese Fischer and Trabert ff 2212 and 2207 s-1, which they regard as a lower bound. The compilation value seems a reasonable compromise. Jonsson, Froese Fischer and Trabert also give a value of 2.154-2 s-1 for the 1S - 3P2 rate with the compilation value is 2.17-2 s-1. We adopt the Fleming et al value as it is the average, but the the differences are trivial at 1 to 2 parts in 216. For the 2s2 1S - 2s3p 1P transition the compilation value is 2.94+10 s-1 while Fritsche and Grant (FG) (Phys Scr 50, 473, 1994) MCDF values are 2.82 and 2.84 +10 s-1 and Froese Fischer, Godefeid and Olsen (J Phy B 30, 1163, 1997) MCHF values are 2.997 and 3.001 +10 s-1. Again we adopt the compilation value but the other values are within 3%. For the 2s2 1S -2s3p 1P there is no compilation value but Hibbert (J Phys B 13, 1721, 1980) on whose work a lot of the assessment depends got a value of 1.76+7 s-1 while Fritsche and Grant obtained 1.61 and 1.67 +7 s-1, Ralchenko and Vainstein got 2.22+7 s- and Froese Fischer, Gaigalas and Godefried (J Phys B 30, 3333, 1997) get 1.96+7 s-1. We adopt the latter value. The values for the 1-20, 2-16, 3-12, 3-15, 3-16, 3-20, 4-14, 4-15, 4-16, 4-20, 5-11, 5-13, 5-17, 5-18, 6-13, 7-13, 8-13, 9-15, 9-16, 10-15, 12-15, 13-17, 13-18, 15-20 and 16-20 are taken from Hibbert. Note that his paper gives the 2s3s 3S -2s3p 1P avalue as 7.65+08 a factor 4 higher than the corresponding 1S - 1P transition. This is treated as an error and avalue of 0 adopted, an earlier paper (Hibbert J Phys B 22, L661, 1979) giving such A values showing those greater than 1 +6 not giving an entry for the 3S -1P transition. THe values of Fleming et al ( MNRAS 279, 1289, 1996) for the 2-3,2-4, and 3-4 are adopted but are within 5% of the compilation. J Lang ----------------------------------------------------------------------- The A-value for 4-2 transition was incorrect. It is replaced by the Fleming et al (MNRAS 279, 1289, 1996) of 1.38E-10s-1. Peter Young, RAL Update : Martin O'Mullane Date : 05-Feb-2003 ----------------------------------------------------------------------- --------------------------------------------------------------------------------- ---------------------------------------------------------------------------------